Lithium Ion Hybrid Batteries

A Laptop in Every Garage

The emergence of small lightweight long-running lithium ion batteries has helped create a market for notebook computers, cell phones, and other portable devices from the iPod to the BlackBerry. Now, efforts to scale that technology for use in car batteries could do for the automotive industry what it did for computer and phone companies. The benefit for consumers could be revolutionary: hybrid or pure electric cars with great efficiency, acceleration and range—at the same price or cheaper than today’s conventional cars.

On Dec. 16, 2005, Toyota announced that they would accelerate development of lithium batteries for use in their hybrids. That’s a clear sign of how important battery power may become for the auto industry. For Toyota to achieve its goals of selling one million hybrids globally per year and offering hybrid versions of all their popular vehicles, they’ll need to reduce the incremental cost of their hybrids. Earlier this year, Katsuaki Watanabe, Toyota’s president, articulated that goal as reducing "the cost difference of hybrids to one-half the current levels." According to Dave Hermance, executive engineer of environmental engineering at Toyota, batteries are the single most expensive element in the hybrid system. "To make a big leap forward with hybrids," he said, "we’ll need a new battery technology."

The current crop of hybrid cars, like the Toyota Prius and the Honda Civic Hybrid, use a combination of gasoline and nickel metal hydride (NiMH) batteries. NiMH is a major step up from the lead acid battery most drivers recognize under their hoods. Battery formulas with nickel, while more powerful than lead acid, have not provided the breakthrough and the long-term cost benefits that battery engineers had hoped. The power of nickel batteries comes from the raw material, which is getting more expensive due to increased demand, while the benefits of lithium batteries are derived from the the mass processing, which can scale to the high volumes required for the rapidly growing hybrid market—without a corresponding jump in price.

The emergence and adoption of advanced lithium batteries could shake up the auto industry. To better understand the changes ahead, several auto companies, including Subaru, Nissan, and Mitsubishi, have produced concept cars that use lithium batteries. Toyota became the first to use lithium ion batteries in a production vehicle when it placed a four-cell lithium pack in its Vitz CVT4, a Scion-looking small boxy vehicle only available in Japan. The Vitz’s battery pack powers the lights, heater, air conditioner, and radio while the car is stopped, allowing the gasoline engine to shut off.

By far, the boldest vision of the lithium future is the Volvo 3CC concept car. Unveiled in 2004, the all-electric vehicle relies exclusively on 3,000 lithium ion cells, each one approximately the size of a common "AA" battery, to provide the equivalent of 105 horsepower with absolutely zero emissions. "We were forced by the current marketplace to use the small format batteries. If we could have done it with less than 3,000 cells, it would have made my life a lot easier," said Ichiro Sugioka, science officer at Volvo’s Monitoring and Concept Center in Camarillo, Calif.

Sugioka was unable to use larger lithium ion batteries more suitable for cars because they don’t commonly exist in the market today. Battery companies trying to create larger lithium batteries, which use cobalt in their formula, quickly encounter a problem known as thermal runaway—which means the batteries can easily catch fire or explode. Not a good idea for cars. However, two enterprising companies, Valence Technologies and A123 Systems have had better results by replacing cobalt with other metals, such as phosphate. Here’s how Valence describes its approach: "Whereas traditional Lithium ion technology utilizes cobalt-oxide cathode material, Saphion® technology incorporates a phosphate based cathode material."

The result is inherently less powerful; however, these two companies’ proprietary technology is working like magic to produce energy storage and charging power similar to cobalt, while avoiding the safety and longevity issue. Yet, the technology still has a way to go—perhaps three to five years—before car-sized lithium batteries are powerful enough, cheap enough, and most importantly, reliable enough to go into mass production vehicles. Pinpointing a date when the first carmaker takes the risk on the new batteries is tough. "The crystal ball on this is real cloudy, but we’ll get there. Lithium ion has too many advantages," said John German, manager of Environmental and Energy Analyses for American Honda.

Business Chemistry
Dozens of smaller companies are racing toward a lithium payday. Some say that their lithium batteries will solve all our transportation problems, and make hydrogen fuel cells immediately irrelevant. The major car companies are not taking the wild claims very seriously, but some battery companies have attracted wider attention. In Nov., A123 Systems, a private company in Watertown Mass., unveiled a lithium battery that earned them $32 million in funding from big name investors, such as Sequoia Capital, Motorola, and the Massachusetts Institute of Technology. The company is working with Department of Energy on the development of lithium ion batteries for hybrid vehicles. Lithium iron phosphate batteries from Valence Technology, a publicly traded company based in Austin, Tex., are being used in Segway electric scooters and a much publicized converted plug-in Prius.

Toyota has spent millions of marketing dollars to make sure that consumers know that current hybrids don’t need be plugged in. But many industry insiders predict that a hybrid with the option to plug in not only represents the next generation of hybrid vehicles, but a major shift in automotive technology. Using a standard home electric plug and outlet, a driver could recharge a car overnight during off-peak hours, and wake up with a vehicle ready to travel 50 or 100 miles without using a drop of gasoline. This can’t happen without more robust batteries (among other things), and the entire industry is looking at lithium batteries as the solution. EDrive Systems, a joint venture between EnergyCS Inc. and Clean-Tech LLC, has created a number of plug-in hybrid prototypes in its effort to commercialize the new technology. EDrive used Valence’s lithium batteries.

The right chemical formula does not necessarily produce a winning business formula. In the first quarter of the 2006 fiscal year, Valence pulled in $3.4 million in revenue, a 20 percent increase from a year ago. But the company, which was founded in 1989, has never recorded a profit. Valence, A123, and other smaller battery makers, could greatly benefit from a partnership with a major car company. Dean Bogues, president of worldwide sales, marketing, and product development for Valence, said that commercialization of their lithium car batteries is not likely to occur overnight via a brand name car company, but will "unfold over time" through partnerships and distribution in commercial fleets. Saft, a battery maker based in France, has entered into such a partnership with DaimlerChrysler by deploying its lithium batteries for use in the car company’s plug-in hybrid Sprinter Van, currently being tested but with no clear plans for production.

Bogues added, "If there was interest from a major OEM [original equipment manufacturer], we wouldn’t turn it down." He explained that it commonly takes 10 years to commercialize new battery chemistry, and places Valence at about three years into that product development cycle.

Small battery companies generally lack experience with auto manufacturers, who can be very demanding from their suppliers. The G.M.s, DaimlerChryslers, Hondas, Fords, and Toyotas of this world want a battery company to deliver a finished integrated system, not just the component cells, electronics, controls, etc. That problem trickles down to another set of players, like Altair Nanotechnologies, who serve the small battery makers with raw materials.

Progress from Within
Toyota, with big hybrid dreams, is not waiting for the small players to deliver. The Japanese maker of the Prius and Highlander Hybrid recently spent $740 million to establish a nine percent ownership stake in Fuji Heavy Industries, which makes advanced hybrid batteries (and Subaru vehicles). In October, Toyota also increased their equity in Panasonic EV Energy from 40 to 60 percent. PEVE, the world’s leading supplier of nickel metal hydride, will act as they key player in Toyota’s recently announced venture to develop a lithium ion battery for hybrid cars.

Johnson Controls is also making a play in the hybrid battery market. In 2002, Johnson Controls acquired Varta, a major European automotive battery manufacturer. In Sept. 2005, they launched a $4 million lab to accelerate work on lithium batteries, and in Oct. signed a memorandum of understanding to work with Saft. Johnson Controls could emerge as the only major U.S.-based hybrid battery maker. The United States is the world’s largest hybrid car market, and all the car companies who manufacture hybrids in the U.S.—Toyota begins production of the Camry Hybrid in 2006—would benefit from having a domestic supplier. If Johnson Controls develops lithium expertise, they will be even better positioned.

Lithium and Gold
The average driver has little or no knowledge of battery chemistry. Small battery companies and large auto companies know exactly what it means: a critical step towards transforming hybrid cars from a niche curiosity to a major revolution in automotive technology. Lithium batteries could be the key. One day not too long ago, we woke up and found ourselves suddenly surrounded by cell phones and laptops. We’re getting closer and closer to the day—probably just beyond the end of this decade—when one or more battery companies hit the right formula and lithium batteries for cars are produced in the millions. Engineers in those companies are like modern day alchemists, trying to turn base materials into gold. If they succeed, they could indeed be very rich.

But the historical alchemists had deeper aspirations. They sought personal spiritual transformation. And the modern day battery alchemists also aspire to loftier goals: a world of personal mobility without auto pollution, global warming, and oil wars.


  • Herman Wiegman

    Your article on the future use of Lithium cells in Hybrids and PHEV’s was right on the mark. Keep your eyes open at the Detroit Auto Show this week and you’ll see some more progress towards “game changing” vehicles from several auto makers.

    Cheers,
    Herman

    wiegman@ieee.org
    wiegman@research.ge.com

  • Monty

    Is it true that If I purchased a SUV Vue Hybrid, in about 5 years the batteries need changing and the cost of each new one would be 5 to 7 thousand dollars?

  • Raymond

    Li-Ion phosphate is the safest, long cycle life battery, the large format phosphate cells are now available in evaluation,
    now looking BMS design house to cooperate with us, the Li-Ion battery BMS required to handle 74S min. up to
    120S cell balance function..

    Please contact us at :
    raymondking@url.com.tw

  • Meathead

    Look at Lithium technologies stock symbol LTHU to get your battery play – Prius test with 125+ MPG see for yourself

  • John Acheson

    The top 4 oil reserves in the world are Saudi Arabia, Canada, Iran and Iraq. The top Lithium reserves are probably all in South America. There’s wars in most all of these regions.

    The top consumers of energy and vehicles in the world are the US, Japan and China. One rules the world, the other isn’t allowed to go to war and China’s expansion has increased demand of every metal including nickel.

    If technology can change the world’s geopolitical situation, what’s more important?

    The pipeline or tanker carrying oil, Lithium or Nickel, or the hi-tech tank and guns guarding the byways and ports?

    Vote with your wallet…

  • Tricky Dick

    I have been flying R/C planes and helicopters for 12 years now. Li-po (Lithium Polymer) has just started to take its place as the power source for any electric aircraft. I have been wondering for a while when the automotive industry was going to start to take advantage of Lithium technologies. In the R/C industry we have Lithium batteries that have a cell count rating of up to 60! That is a lot! What a cell count is is how much power you can draw from that particular battery without harming the chemical structure. I am actually going to my local Ford dealer today to purchase a Hybrid Escape, if someone hasn’t beaten me to it. I can only hope that when the Ni-Cd batteries fail on me 5-7 years down the road (which is a strong possibility) that I will be able to convert it from Ni-Cd to Li-ion, Li-po or Li-mg (lithium magnesium) and that I can put a Lithium charger in it. Or that the new hybrids or battery operated autos will not be overly priced because of supply and demand. And why are none of these automotive companies looking into using brush-less motors instead of brushed motors to power the automobiles. For R/C, brush-less motors are 95% efficient, compared to brushed motors which are way less efficient. Go Lithium already auto companies you wont be disappointed an neither will you consumers.

  • Greg

    I am not posititve but I think all of the proprietary rights for producing Li-Ion batteries are owned by a subsidiary of Chevron, and they have good reason to keep the size of batteries as such that they will not hurt oil consumption.

  • bk

    I hope you realize that Chevron could never preventing Li-Ion technology from overtaking oil (if ever someone developed a way that it could). Chevron would be forced to accept a royalty agreement of some sort! If they wouldn’t they’d be hung to burn like a witch from the middle ages.

  • m Larsen

    Where is the discussion of super capacitors that may be an integral part of battery powered electric systems?

  • JACK CARLE

    I AM A NORMAL PERSON WITH AN IDEA AND I NEED SOME INFO.

    1. IS IT TRUE THAT HEAT DESTROYS BATTERIES?
    2. BATTERIES GENERATE HEAT WHEN BEING USED?
    2. YOU WANT BATTERIES TO BE SMALL BUT HAVE A BIG SURFACE TO GENERATE ELECTRICITY. EXP. CURRENT CAR BATTERIES HAVE X SQUARE INCHES OF LEAD PLATES IN THEM.
    WHAT WOULD YOU SAY IF I COULD PUT 3 TIMES AS MUCH LEAD IN THE SAME SPACE? I COULD ALSO DO THIS WITH LITHIUM OR ANY OTHER METAL. WOULDN’T THIS MAKE A BATTERY THAT WOULD HOLD ELECTRICY LONGER? I THINK I CAN ALSO DISSAPATE THE HEAT ALONG WITH THIS.

    WHAT I HAVE IS JUST AN IDEA BUT I HAVE THE CAPABILITY TO PROVE IT WHEN I CAN GET MORE INFORMATION ON WHAT IS NEEDED.

    I WOULD APPRECIATE TALKING WITH SOMEONE ON THIS SUBJECT . THANK YOU JACK CARLE

  • RJ

    Look up Tesla Motors and see what they have done. A pure electric 220 mile per charge sports car with acceleration of under 4.0 seconds. They are not cheap but very cool cars using Lithium batteries. It can be done. It has been done.

  • Adam

    Nice idea…what information are you looking for..

    Adam

  • richard albonizio

    Check out Hybrid Technologies Corp. They have a factory up and running in North Carolina.

  • Arthur Lee

    We make battery specialised in Lithium ion, LiFePo4 Li-ion and polymer lithium ion.

    Contact me if you are interested.

    http://www.kayobattery.com

    arthur@kayobattery.com

  • OzzyOz

    Can’t happen fast enough! Running an EV 100% off Li-Ion batteries would allow a $5/week power bill to run your car Vs the current $70/week av fuel bill. the ICE (Internal Combustion Engine) either run on petrol (75% inefficient) or diesel (60% inefficient) both + 40% transmission losses, is so inefficient I’m sure most people don’t realise that up to 85% of the fuel purchased to run a vehicle is waisted as heat. Only 15% of the energy in each litre of fuel pushes the car forward. Electric motors mounted at the wheels running straight off batteries will be close to 99% efficient plus more advanced re-generation braking to top up the ‘tanks’ and that’s where huge savings are to be made. Li-Ion batteries will allow EV’s with acceptable range and performance to make this happen.

  • sheila mant

    what are they made of?

  • GingerLy

    Hi, i’m an 8th grader doing History Day, and my research focuses on Lithium-ion Battery, including the advancements in hybrid and electric cars. Can anybody telll me who’s in charge of this article please? If thats even possible to find out of course…

  • ericbecky

    You can contact the site owner, Brad Berman, through the contact page at
    http://www.hybridcars.com/contact

    Eric Powers
    HybridCars.com Moderator
    Green Drive Expo Organizer (See you there!)

  • meme

    hey tis idea is awsome and so are you

  • curtis spear

    Several months ago there was an article in a newspaper concerning a Li battery that could offer 80 miles per charge for the Volt coming out in the near future. I would appreciate information on the company making this battery.

  • calvin

    The Volt’s battery pack will only power the car for 40 miles on electricity alone. Car companies like to put fantasy technology in their concept cars and prototypes. GM has gone a step further than most manufacturers by actually including the non-existent fantasy technologies in their press releases for production vehicles. This helps to generate buzz for GM while dampening public interest in their competitors’ products which are based on real technologies.

    That said, any type of battery can power a vehicle for 80 miles if you put enough of them together. It’s just expensive and heavy.

  • david weigand

    are there any obvious places to start looking for sponsors to $$ help me addon elec pow to the flathead in my 52 Ford panel trukster, i have the mech/engineering exp to do the deed but like the rest of yall lack the $$$. any sugg will be appreciated. thanx

  • Bruce

    I’ve thought about electric cars for a long time and wondered about what part the electrical system might play in greater distance. For instance, would an electrical system with wire containing less ohms of resistance, allowing electricity to flow easier give longer battery life?

  • paula curington

    please let me know the most cheapest prius avaliable in austin or in georgetown, Texas

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  • Jarvis

    http://www.prietobattery.com has some good info about batteries.

  • Curtiss C Price Sr.

    4 years, to this day all I see is cars,cars,cars,. What about a small ION battery powered pickup.Us DIY need a small pickup bed for 2×4 or a bag of cement, potting soil, does anybody in the auto indistury think: Service personel need places to put tools, parts, what ever. Someone is NOT DOING THEIR JOB, Curtiss

  • becky

    We are specialised in battery testing equipment.

    Contact me if you are interested.

    suxiaohong@neware.com.cn

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  • G.W. Jensen

    Bob Albertson, the inventor of the Weed Eater, is building a pickup truck that is all electric, and will go 300 miles on a charge. He is locate in Alma, WI, and the name of his company is MAG-TRANS Corp. His Phone No. is 608-248-2100.

  • G.W. Jensen

    Bob Albertson, the inventor of the Weed Eater, is building an all electric truck that he claims can go 300 miles on a charge. He is located in Alma, WI, and his phone no. is 608-248-2100. You can see his truck demonstrated on his website: Bob Albertson, Mag-Trans Corp.

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